Synthesis and characterization of unusual oxidorhenium(V) cores

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dc.contributor.author	Nguyen, H.H.
dc.contributor.author	Hazin, K.
dc.contributor.author	Abram, U.
dc.date.accessioned	2011-05-05T03:39:40Z
dc.date.available	2011-05-05T03:39:40Z
dc.date.issued	2011
dc.identifier.citation	Issue: 1 Page : 78-82	vi
dc.identifier.issn	14341948
dc.identifier.uri	http://tainguyenso.vnu.edu.vn/jspui/handle/123456789/6604
dc.description.abstract	Reactions of (NBu4)[ReOCl4] with N-(N??, N??-dialkylaminothiocarbonyl)-N?-(2- hydroxyphenyl)benzamidines (H2L1) give complexes of the compositions [ReOCl(L 1)] (1), cis-[ReO(L1 )(OMe)] (2), or cis,cis-[{ReO(L 1)}2O] (3) depending on the conditions applied. Compound 3 contains a bridging oxygen atom in the cis position to the terminal oxido ligands of both rhenium atoms. The analogous dimeric, sulfur-bridged compound [{ReO(L1)}2S] (4) was obtained by the reaction of 1 with Na2S. Complexes with the unusual oxidorhenium(V) cores, cis-{ReO(OR)}3+, cis,cis-{ORe-O-ReO}4+, and cis,cis-{ORe-S-ReO}4+, are formed from the reaction of [ReOCl 4]- and N-(N??,N??- dialkylaminothiocarbonyl)- N?-(2-hydroxyphenyl)benzamidine ligands depending on the conditions applied. Copyright ?? 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.	vi
dc.language.iso	en	vi
dc.publisher	European Journal of Inorganic Chemistry	vi
dc.subject	Bridging ligands	vi
dc.subject	Coordination modes	vi
dc.subject	Oxido cores	vi
dc.subject	Rhenium	vi
dc.title	Synthesis and characterization of unusual oxidorhenium(V) cores	vi
dc.type	Article	vi

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