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Title: | Dimeric azaphilones from the xylariaceous ascomycete Hypoxylon rutilum |
Authors: | Quang D.N. Hashimoto T. Stadler M. Asakawa Y. |
Keywords: | Dimeric azaphilones Fungi Hypoxylon rutilum Rutilin Xylariaceae |
Issue Date: | 2005 |
Publisher: | Tetrahedron |
Citation: | Volume 61, Issue 35, Page 8451-8455 |
Abstract: | Fractionation of the methanolic extract of the stromata of Hypoxylon rutilum (Xylariaceae, Ascomycetes) resulted in the isolation of two novel dimeric azaphilones named rutilins A and B, together with the known compounds, entonaemin A, and rubiginosins A and B. Their structures were elucidated by 2D NMR, HR-MS, IR and UV spectroscopy. Rutilins A and B are presumably synthesized via specific biogenic aldol condensations of mitorubrinol acetate moieties with rubiginosins A and B, respectively. The resulting dimeric azaphilone scaffold of the rutilins is unprecedented in nature. © 2005 Elsevier Ltd. All rights reserved. |
URI: | http://tainguyenso.vnu.edu.vn/jspui/handle/123456789/11666 |
ISSN: | 404020 |
Appears in Collections: | Articles of Universities of Vietnam from Scopus
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