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Title: | Metastable dimethyl phthalate molecular ions: Does the loss of a methoxyl radical proceed with or without anchimeric assistance? |
Authors: | Gerbaux P. De Winter J. Flammang R. Nguyen V.S. Nguyen M.T. |
Keywords: | Collisional activation Dimethyl phthalate Metastable ion Quantum chemical calculation |
Issue Date: | 2010 |
Publisher: | International Journal of Mass Spectrometry |
Citation: | Volume 290, Issue 3-Feb, Page 127-132 |
Abstract: | Using MS/MS/MS experiments and quantum chemical calculations, it is demonstrated that oxygen (carbonyl) methylated phthalic anhydride cations are produced when metastable dimethyl phthalate molecular ions expel a methoxyl radical. At higher internal energies, isomeric acyl ions are competitively generated. © 2009 Elsevier B.V. All rights reserved. |
URI: | http://tainguyenso.vnu.edu.vn/jspui/handle/123456789/13202 |
ISSN: | 13873806 |
Appears in Collections: | New - Articles of Universities of Vietnam from Scopus
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