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Tai Nguyen So - Vietnam National University, Ha Noi - VNU >
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| Title: | Formation of metallacyclic complexes by activation of an aryl C - H bond in a platinum-safrole analogue of Zeise's salt |
| Authors: | Da T.T.
Kim Y.-M.
Chi N.T.T.
Chien L.X.
Van Minh N.
Dinh N.H. |
| Keywords: | |
| Issue Date: | 2008 |
| Publisher: | Organometallics |
| Citation: | Volume 27, Issue 14, Page 3611-3613 |
| Abstract: | Potassium trichloro(safrole)platinate(II), K[Pt-(Saf)Cl3] (1), reacts with piperidine to give cis-[Pt(Saf1H)(Piperidine)Cl] (2). The interaction of 1 with AgNO3, SnCl2, KOH, and ethanol-water solutions leads to formation of the dinuclear chelate ring complex [Pt 2(Saf-1H)2Cl2] (3). 1H and 13C NMR spectra and single-crystal X-ray diffraction show that in complexes 2 and 3 deprotonated safrole is bound up with platinum(II) both at a benzene carbon and at the ethylenic double bond of the side chain. © 2008 American Chemical Society. |
| URI: | http://tainguyenso.vnu.edu.vn/jspui/handle/123456789/13599 |
| ISSN: | 2767333 |
| Appears in Collections: | New - Articles of Universities of Vietnam from Scopus
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