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Please use this identifier to cite or link to this item: http://tainguyenso.vnu.edu.vn/jspui/handle/123456789/794

Title: Model of conductivity for perovskites based on the scaling property of grain boundary
Authors: Phung, Quoc Thanh
Bach, Thanh Cong
Hoang, Nam Nhat
Keywords: Percolation-theory model
Perovskites
Grain boundary
Issue Date: 2005
Publisher: ĐHQGHN
Citation: VNU. JOURNAL OF SCIENCE, Mathematics - Physics. T.XXI, N04 - 2005
Abstract: We present the percolation-theory model for explanation of conductivity of perovskites based on the scaling property of grain boundary formation. Assuming a two-layer simple effective medium model, composed of the grain itself as a first layer and the boundary as a second layer, it was modeled that the net resistivity r of the medium depends on the average grain size L, boundary thickness L' and boundary fractal dimension D. The obtained formula was tested specifically for the perovskite system Ca$_{0.85}$Pr$_{0.15}$Mn$_{1-x}$Ru$_x$O$_3$ (x=0.00, 0.03, 0.05 and 0.07) whose structures and electric properties were reported earlier by these authors [VNU J. of Sci., XX, No.3 AP, 2004, p. 130-132]. The determination of fractal dimension was based on the standard length-area technique and was carried out using SEM images which were photographed at three magnification scales 2, 5 and 10$\mu$m. This dimension showed good correspondence to the small polaron hoping energy in high temperature region and gave very good fits to experimental data for T$
Description: VNU. JOURNAL OF SCIENCE, Mathematics - Physics. Vol. 21, No.4 - 2005
URI: http://hdl.handle.net/123456789/794
ISSN: 0866-8612
Appears in Collections:Vol. 21, No.4

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